- Titel
- Mechanistic insights into the reversible lithium storage in an open porous carbon via metal cluster formation in all solid-state batteries
- Zitierfähige Url:
- https://nbn-resolving.org/urn:nbn:de:bsz:14-qucosa2-837863
- Quellenangabe
- Carbon
Jahrgang: 188
Heft: 2022
Seiten: 325-335
ISSN: 0008-6223 - Erstveröffentlichung
- 2022
- Abstract (EN)
- Porous carbons are promising anode materials for next generation lithium batteries due to their large lithium storage capacities. However, their highsloping capacity during lithiation and delithiation as well as capacity fading due to intense formation of solid electrolyte interphase (SEI) limit their gravimetric and volumetric energy densities. Herein we compare a microporous carbide derived carbon material (MPC) as promising future anode for all solid state batteries with a commercial high performance hard carbon anode. The MPC obtains high and reversible lithiation capacities of 1000 mAh g 1 carbon in half cells exhibiting an extended plateau region near 0 V vs. Li/Liþ preferable for full cell application. The well defined microporosity of the MPC with a specific surface area of >1500 m2 g 1 combines well with the argyrodite type electrolyte (Li6PS5Cl) suppressing extensive SEI formation to deliver high coulombic efficiencies. Preliminary full cell measurements vs. nickel rich NMC cathodes (LiNi0.9Co0.05Mn0.05O2) provide a considerably improved average potential of 3.76 V leading to a projected energy density as high as 449 Wh kg 1 and reversible cycling for more than 60 cycles. 7Li Nuclear Magnetic Resonance spectroscopy was combined with ex situ Small Angle X ray Scattering to elucidate the storage mechanism of lithium inside the carbon matrix. The formation of extended quasi metallic lithium clusters after electrochemical lithiation was revealed.
- Andere Ausgabe
- Link zum Artikel der zuerst in der Zeitschrift ”Carbon“ bei Elsevier Science erschienen ist.
DOI: 10.1016/j.carbon.2021.11.061 - Freie Schlagwörter (DE)
- Alle Festkörperbatterien, Mikroporöser Kohlenstoff, Lithium-Batterie, Anode, Kohlenstoff auf Karbidbasis, Lithium-Cluster
- Freie Schlagwörter (EN)
- All solid-state battery, Microporous carbon, Lithium battery, Anode, Carbide-derived carbon, Lithium cluster
- Klassifikation (DDC)
- 540
- Verlag
- Elsevier Science, Amsterdam
- Version / Begutachtungsstatus
- angenommene Version / Postprint / Autorenversion
- URN Qucosa
- urn:nbn:de:bsz:14-qucosa2-837863
- Veröffentlichungsdatum Qucosa
- 02.03.2023
- Dokumenttyp
- Artikel
- Sprache des Dokumentes
- Englisch
- Lizenz / Rechtehinweis
